The Main
Effects on Polymers Exposed to UV
All types of UV can cause a photochemical
effect within the polymer structure, which
can be
either a benefit or lead to degradation
of some sort to the material. Note that
compared to our skin, the higher energy
UVC is more likely to affect plastics.
Degradation
The main visible effects are a chalky
appearance and a color shift. The component
surface may also become brittle. I can vouch
for these effects as found in my children’s
red polypropylene (PP) monkey bars. After
a few years in the garden the extruded pipes
retained their full color, while the injection
molded clamp parts became white and cracked.
Other components likely to be affected by
solar exposure include stadium seats, outdoor
furniture, greenhouse films, window frames
and automotive parts.
Some plastics
have been exposed to much harsher radiation
levels than we experience on earth. Components
in the Hubble Space Telescope (HST) and
the International Space Station (ISS) require
plastics that can survive the demands of
outer space. Fluoropolymers such as FEP
and polyimides like Kapton are plastics
which have been successfully used for the
HST and ISS.
The above
effects are predominantly in the surface
layer of the material and are unlikely to
extend to depths above 0.5mm into the structure.
However, stress concentrations caused by
the highly brittle nature of some commodity
plastics may well lead to a complete failure
of the component.
Benefits
Many of us will be using of the main
benefits from UV radiation of protective
polymeric coatings, such as
polyurethane-acrylates, on exterior
automobile components, which have been
cured by UV. A more local benefit for
many people will be the UV radiation in
counter top purifiers and water coolers
which is often assisted by the good
transmission properties of FEP
(Fluorinated Ethylene Propylene) tubing
and its ability not to degrade.
Melt-processable FEP is also used as a
protective coating on UV lamps for
electronic fly killers, where the
coating allows for excellent
transmission (only around 4% loss for a
0.25mm film). There are also many
applications for UV, including curing of
inks on plastic substrates, and UVC
radiation for sterilization of
components.
UV
Resistance at Zeus
Zeus tubing is virtually unaffected by
weather or prolonged exposure to
ultraviolet light. Where applications demand
complete dependability in these
conditions, fluoropolymers are the
answer. Resistance to extreme heat,
cold, and ultraviolet light encountered
in radar and other electronic
components, such as antenna bushings,
are excellent examples of the value of
this material in these applications.
Ultraviolet transmittance can be another
useful aspect of fluoropolymer tubing.
While levels of UV transmittance vary
among the fluoropolymer resin family,
Zeus tubing is used in applications such
as water purification with excellent
results. Crystallinity and wall
thickness also affect the level of
transmittance tubing will allow.
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Request Samples and Tech Info
If you would like samples of our fluoropolymer or other engineered tubing, or would
like to discuss a specific application, we'd like to talk with you. Zeus has a generous
sample program, making it easier than ever for engineers and designers to get stock
and custom samples quickly. Click here to contact us now.
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"Offering custom Teflon® tubing and Teflon®
heat shrinkable tubing as well as tubing
and heat shrink made from fluoropolymer
resins such as PTFE, FEP, PFA, ETFE, PEEK,
and more."
Teflon®
is a registered trademark of
DuPont
PEEK is a trademark of
Victrex
PLC
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